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Updated: Feb 4, 2026

Measuring Dissolved Methane in Aquatic Ecosystems Using An Optical Spectroscopy Gas Analyzer
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Simultaneous Dissolved Gas Analysis in Transformer Oil via Time-Division-Multiplexed Quartz-Enhanced Photoacoustic

Jialiang Dai1,2, Yixin Zhang1,2, Jiapeng Wang1,2

  • 1State Key Laboratory of Quantum Optics Technologies and Devices, Institute of Laser Spectroscopy, Shanxi University, Taiyuan 030006, China.

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This study introduces a novel quartz-enhanced photoacoustic spectroscopy (QEPAS) system for simultaneous detection of acetylene and methane in transformer oil. The system offers high sensitivity and low sample volume, enabling early fault detection.

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Area of Science:

  • Electrical Engineering
  • Analytical Chemistry
  • Materials Science

Background:

  • Dissolved gas analysis (DGA) is crucial for diagnosing faults in oil-immersed transformers.
  • Acetylene (C2H2) and methane (CH4) are key indicator gases for transformer fault identification.
  • Current DGA methods may require larger sample volumes and lack real-time monitoring capabilities.

Purpose of the Study:

  • To develop and demonstrate a time-division-multiplexed quartz-enhanced photoacoustic spectroscopy (QEPAS) sensing system.
  • To achieve simultaneous and sensitive detection of dissolved acetylene (C2H2) and methane (CH4) in transformer oil.
  • To enable real-time monitoring and analysis of dissolved gases with reduced sample volume.

Main Methods:

  • Utilized a time-division-multiplexed QEPAS sensing system with an on-beam configuration.
  • Integrated headspace degassing with QEPAS for real-time analysis.
  • Measured minimum detection limits (MDLs) for C2H2 and CH4.

Main Results:

  • Achieved MDLs of approximately 15 ppb for C2H2 and 0.3 ppm for CH4, significantly below industry safety thresholds.
  • Demonstrated a 20-fold enhancement in signal amplitude due to the on-beam configuration.
  • The system requires a minimal gas cell volume of ~1.6 mL, reducing oil sample consumption.

Conclusions:

  • The developed QEPAS system offers high sensitivity, rapid response, and low sample consumption for DGA.
  • It provides a viable and efficient approach for early detection of transformer faults.
  • This work lays the foundation for applying QEPAS in dissolved gas analysis for transformer monitoring.