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Polymers02:34

Polymers

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The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
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Pyruvate is the end product of glycolysis, where glucose is oxidized to pyruvate, simultaneously reducing NAD+ to NADH. Two molecules of ATP are also produced by substrate-level phosphorylation.
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Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)01:20

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Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
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Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)01:22

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Vicinal or three-bond coupling is commonly observed between protons attached to adjacent carbons. Here, nuclear spin information is primarily transferred via electron spin interactions between adjacent C‑H bond orbitals. This generally favors the antiparallel arrangement of spins, so 3J values are usually positive.
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Some individuals interpret life events as a consequence of their personal choices and actions, while others believe that outcomes are dictated by fate or destiny. This divergence in perspective has been examined in psychological and cross-cultural studies, particularly in relation to religious faith and cultural beliefs about causality.Fate and Personal ResponsibilityPeople who emphasize personal responsibility view events as direct consequences of their decisions. For instance, breaking a leg...
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Rewriting Polymer Fate via Chemomechanical Coupling.

Jiahe Huang1, Haohui Zhang2, Jiehao Chen2

  • 1School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia, USA.

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Summary
This summary is machine-generated.

Researchers developed a "living" polymer that can continuously grow, shrink, and heal after fabrication. This sustainable material can be reprogrammed for advanced electronics and soft robotics.

Keywords:
chemomechanicsdynamic polymersgrowable soft electronicstransformable soft robots

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Area of Science:

  • Polymer Chemistry
  • Materials Science
  • Chemomechanics

Background:

  • Synthetic polymers typically lack dynamic life-like properties such as growth, self-healing, or post-fabrication property alteration.
  • Existing materials are often static, limiting their application lifespan and adaptability.

Purpose of the Study:

  • To engineer a synthetic polymer platform with continuous, life-like abilities including growth, degrowth, healing, and property reprogramming.
  • To integrate dynamic processes like mass transport, reversible polymerization, and chain exchange into a single chemomechanically coupled network.

Main Methods:

  • Coupling theoretical modeling with experimental validation to create an open-system polymer platform.
  • Utilizing light-activated catalysts for microscale control over polymer growth and degrowth.
  • Implementing reversible polymerization and chain exchange mechanisms for dynamic network evolution.
  • Integrating mass transport and stress to achieve a fully chemomechanically coupled system.

Main Results:

  • Demonstrated a polymer platform capable of continuous growth and degrowth with precise microscale control.
  • Achieved on-demand reprogramming of polymer chemical composition, enabling modulus tuning across two orders of magnitude.
  • Showcased the material's ability to heal and adapt its properties after initial fabrication.

Conclusions:

  • Established a foundation for sustainable, endlessly reprogrammable polymers with life-like dynamic capabilities.
  • The developed living polymer platform enables applications in self-growable electronics, advanced soft robotics, and self-regenerating devices.
  • This work opens new avenues for materials that can adapt and evolve throughout their lifecycle.