Reaction mechanism of PET conversion to 1,4-cyclohexanedimethanol and p-xylene via halogen hydride depolymerization...

Upcycling plastics polyethylene terephthalate (PET) into high-value products while simultaneously achieving in situ regeneration of halogen hydride (HF, HCl, and HBr) from halogen-containing waste using intermediate compounds as carriers represents a dual-benefit pathway. However, the evolutionary behavior and decomposition mechanisms remain unclear, posing significant challenges. Herein, theoretical and experimental approaches are employed to elucidate a tandem method involving halogen hydride-assisted depolymerization and hydrogenation for converting waste PET into valuable products 1,4-cyclohexanedimethanol (CHDM) and p-xylene (PX). The research demonstrates that the directional conversion of PET to CHDM and PX occurs in two distinct stages: the first stage involves PET depolymerization via halogen acids to generate intermediate carrier compounds 1,4-benzenedicarbonyl difluoride, terephthaloyl chloride, and 1,4-benzenedicarbonyl dibromide, with rate-determining step barriers of approximately 153 kJ/mol, 132 kJ/mol, and 123 kJ/mol, respectively; the second stage entails hydrogenation of these intermediates to regenerate HF, HCl, and HBr in situ while producing CHDM and PX. Notably, the presence of water during the hydrogenation stage inhibits the formation of PX and CHDM. This study not only enables effective control of halogen-containing waste to reduce the corrosivity risk of HF but also achieves reduction in energy consumption, offering a novel strategy for the resource utilization of polyester waste plastics and halogenated wastes.