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Controlled ROS generation in pyridinium-functionalized nanocatalysts for selective photooxidation
Jing-Wang Cui1,2, Shuai Ma1, Yun-Rui Chen1
1MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, P. R. China. zhangjie68@bit.edu.cn.
Abstract:
A pyridinium-functionalized CP was ultrasonically transformed into nanoparticles, delivering a recyclable photocatalyst for selective alcohol oxidation. Notably, water addition triggers 1O2 generation via ˙O2- and H2O interactions, markedly boosting selectivity. This work presents the first exploration of pyridinium-bearing CPs functioning as nanocatalysts for controlled photooxidation.
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