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Published on: October 1, 2019
Highly Transparent Lead Halides Bmpip2PbBr4 Single Crystals for X-Ray Imaging and Versatile Ionizing Radiation
Haitao Tang1, Wusheng Zou2, Yong Liu1
1Key Lab of Artificial Micro- and Nano-Structures of Ministry of Education of China, School of Physics and Technology, Wuhan University, Wuhan, China.
A novel organic metal halide single crystal, Bmpip2PbBr4, effectively detects multiple ionizing radiations including X-rays, gamma rays, and neutrons. This versatile scintillator offers high optical transparency and luminescent performance for advanced radiation detection applications.
Area of Science:
- Materials Science
- Nuclear Physics
- Optoelectronics
Background:
- Metal halides are promising for optoelectronic devices and radiation detectors.
- Developing single scintillators for diverse ionizing radiation (X-rays, gamma rays, neutrons) is challenging due to varying absorption cross-sections.
Purpose of the Study:
- To report a novel 0D organic metal halide hybrid single crystal, Bmpip2PbBr4, for multifarious ionizing radiation detection.
- To investigate its optical and luminescent properties for scintillator applications.
Main Methods:
- Synthesis and characterization of the Bmpip2PbBr4 single crystal.
- Evaluation of optical transparency and photoluminescence quantum yield (PLQY).
- Measurement of light yields under X-ray and gamma-ray (22Na) irradiation.
- Testing detection capabilities for alpha particles, beta particles, gamma rays, and neutrons.
Main Results:
- Bmpip2PbBr4 exhibits high optical transparency (98.90%) and excellent luminescence (PLQY = 48.14, lifetime = 63.50).
- Achieved high light yields of 21,000±800 photons MeV-1 for X-rays and 16,000 photons MeV-1 for 22Na gamma rays.
- Demonstrated effective detection of alpha particles, beta particles, gamma rays, and neutrons.
Conclusions:
- Bmpip2PbBr4 single crystals show potential as versatile scintillators.
- The material is suitable for X-ray imaging and broad ionizing radiation detection.
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