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Reversible Deactivation Radical Polymerization in Biomass-Derived Solvents: Sustainable Approach in Polymer Chemistry
Agata Hochół1,2, Izabela Zaborniak1, Magdalena Bednarenko1
1Department of Physical Chemistry, Faculty of Chemistry, Rzeszow University of Technology, Al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland.
ACS Polymers Au
|February 9, 2026
Summary
This review explores green solvents from renewable resources for reversible deactivation radical polymerization (RDRP). Biobased solvents show promise for sustainable and eco-friendly polymer synthesis.
Area of Science:
- Polymer Chemistry
- Green Chemistry
Background:
- Conventional organic solvents pose risks to human health and the environment.
- There is a growing need for sustainable alternatives in chemical synthesis.
Purpose of the Study:
- To review advancements in using renewable resource-derived solvents for reversible deactivation radical polymerization (RDRP).
- To evaluate the effectiveness and benefits of green solvents, particularly biobased options, in controlled polymer synthesis.
Main Methods:
- Literature review focusing on RDRP techniques and solvent applications.
- Classification and evaluation of solvent parameters for green chemistry.
- Detailed examination of biomass-derived solvents (lignocellulosic, essential, and vegetable oils).
Main Results:
- Biobased solvents are effective alternatives to traditional organic solvents in RDRP.
- These sustainable solvents address resource depletion and environmental concerns.
- Promising outcomes demonstrate enhanced sustainability in controlled polymer synthesis.
Conclusions:
- Renewable resource-derived solvents are viable for RDRP.
- Biobased solvents offer a pathway to greener polymer synthesis.
- Further research into these sustainable alternatives is warranted for environmental compatibility.
Keywords:
RDRPbiomass-derived solventsessential oilsgreen chemistrylignocellulosic biomasspolymer synthesissolvent effectvegetable oilsMore Related Videos
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