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Removal of Microplastics from Drinking Water by Moringa oleifera Seed: Comparative Performance with Alum in Direct
Gabrielle S Batista1, Victoria A S Ferreira1, Luiz G R Godoy1
1São Paulo State University (UNESP), Institute of Science and Technology, Environmental Engineering Department, São José dos Campos 12247-016, Brazil.
Abstract:
In this study, the removal efficiency of aged polyvinyl chloride microplastics (Aged-PVC MPs) from low-turbidity drinking water using Moringa oleifera seed saline extract (MOS-SE) and aluminum sulfate (alum) in direct filtration (coagulation-flocculation-filtration) and in-line filtration (coagulation-filtration) systems is investigated. Aged-PVC MPs (15 mg/L, D50 = 15.0 μm) and humic acid (10 mg/L) were spiked into synthetic water to evaluate removal performance across pH 5.0-8.0. The optimal conditions achieved >98% turbidity removal with 30 mg/L MOS-SE and 9 mg/L alum at a pH of 6.0, corresponding to 98.5% and 98.7% of Aged-PVC MP removal, respectively, as confirmed by scanning electron microscopy particle counting. Although nonintrusive floc imaging revealed differences between coagulated (43-46 μm) and flocculated aggregates (61-66 μm), in-line filtration performs equivalently to direct filtration in terms of MP removal, demonstrating that direct filtration's flocculation step was unnecessary. MOS-SE exhibited superior performance across broader pH ranges (5.0-8.0) compared with alum (5.0-7.0). While MOS-SE increased dissolved organic carbon because of residual organic matter, it effectively reduced specific ultraviolet absorbance (SUVA) by 88%, indicating efficient removal of aromatic natural organic matter. These findings demonstrate the viability of Moringa oleifera as a sustainable alternative for MP removal in drinking water treatment via in-line filtration.
Insights
Moringa oleifera seed extract effectively removes aged PVC microplastics from drinking water using in-line filtration. This sustainable method matches direct filtration performance, offering a promising alternative for water treatment.
Area of Science:
- Environmental Science
- Water Treatment Technology
- Materials Science
Background:
- Microplastic pollution, specifically aged polyvinyl chloride (Aged-PVC MPs), poses a significant challenge in drinking water sources.
- Conventional water treatment methods may not fully address the removal of microplastics.
- Natural coagulants offer potential sustainable solutions for water purification.
Purpose of the Study:
- To investigate the efficacy of Moringa oleifera seed saline extract (MOS-SE) and aluminum sulfate (alum) for removing Aged-PVC MPs from drinking water.
- To compare the performance of direct filtration (coagulation-flocculation-filtration) and in-line filtration (coagulation-filtration) systems.
- To evaluate removal efficiency across a range of pH conditions (5.0-8.0).
Main Methods:
- Aged-PVC MPs and humic acid were spiked into synthetic low-turbidity water.
- Experiments were conducted using direct filtration and in-line filtration systems with MOS-SE and alum.
- Removal efficiencies were assessed via turbidity measurements and scanning electron microscopy particle counting.
- Floc characteristics were analyzed using nonintrusive floc imaging.
- Dissolved organic carbon (DOC) and specific ultraviolet absorbance (SUVA) were measured to evaluate organic matter removal.
Main Results:
- Both MOS-SE and alum achieved >98% turbidity removal and >98% Aged-PVC MP removal at optimal conditions (pH 6.0).
- In-line filtration demonstrated equivalent microplastic removal efficiency to direct filtration, rendering the flocculation step unnecessary.
- MOS-SE showed superior performance across a broader pH range (5.0-8.0) compared to alum (5.0-7.0).
- MOS-SE effectively reduced aromatic natural organic matter, evidenced by an 88% decrease in SUVA, despite a slight increase in DOC.
Conclusions:
- Moringa oleifera seed saline extract is a viable and sustainable alternative for microplastic removal in drinking water treatment.
- In-line filtration is an efficient and simplified approach for microplastic removal, eliminating the need for a separate flocculation step.
- The study highlights the potential of natural coagulants like MOS-SE for advanced water purification technologies.
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