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Updated: Feb 10, 2026

Synthesis and Functionalization of 3D Nano-graphene Materials: Graphene Aerogels and Graphene Macro Assemblies
Published on: November 5, 2015
Carbon Dioxide Adsorption Using Porous 3D Self-Assembled Graphene.
Bharat Nayak1, Maulik Gauswami1, Lavanya Yalagandula2
1Department of Chemical Engineering, Birla Institute of Technology and Science Pilani, Pilani 333031, Rajasthan, India.
Highly porous 3D self-assembled graphene (SAG) was synthesized for carbon capture. This material shows significant carbon dioxide (CO2) uptake and high selectivity for CO2/H2 and CO2/CH4 separations.
Area of Science:
- Materials Science
- Chemical Engineering
- Environmental Science
Background:
- Rising carbon emissions necessitate efficient and cost-effective capture technologies.
- Graphene-based materials offer potential for gas adsorption due to their unique properties.
Purpose of the Study:
- To synthesize and characterize 3D self-assembled graphene (SAG) for gas adsorption.
- To evaluate SAG's performance for carbon dioxide (CO2) capture and separation.
Main Methods:
- One-step hydrothermal synthesis for SAG.
- Characterization using HRTEM, FESEM, PXRD, BET, Raman, FTIR, and HRXRD.
- Measurement of CO2, H2, and CH4 adsorption isotherms from 0.1 to 30 bar.
Main Results:
- 3D SAG exhibited a CO2 uptake of approximately 2.18 mmol/g.
- High ideal gas selectivity was observed: 59.38 for CO2/H2 and 10.51 for CO2/CH4 at 0.1 bar.
- The material demonstrated excellent adsorption properties for CO2.
Conclusions:
- 3D SAG is a promising material for CO2 capture and separation.
- The synthesized material shows potential for various gas adsorption applications.
- The cost-effective synthesis route makes SAG an attractive option for industrial applications.
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