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Published on: March 15, 2017
Interlayer-Expanded Metal Oxide/Sulfide Composites for Ultrastable Flexible Hybrid Supercapacitors.
Sara Yaseen1,2,3, Kashif Mairaj Deen2, Edouard Asselin2
1Institute of Physics, Khwaja Fareed University of Engineering and Information Technology, Rahim Yar Khan 64200, Pakistan.
Researchers developed a novel molybdate-ion intercalated oxide/sulfide composite (ZnMoO4/CoMoS4) for advanced energy storage. This material significantly boosts supercapacitor performance, offering high energy and power densities for flexible devices.
Area of Science:
- Materials Science
- Electrochemistry
- Energy Storage
Background:
- Optimizing electrode nanoarchitectures is key for high-performance batteries.
- Improving redox kinetics enhances energy and power density simultaneously.
Purpose of the Study:
- To engineer a molybdate-ion intercalated oxide/sulfide composite for superior electrochemical behavior.
- To enhance pseudocapacitive contributions through precise control of the active site's chemical environment and electronic structure.
Main Methods:
- Hydrothermal synthesis of ZnMoO4/CoMoS4 nanostructures anchored on Cu foil.
- Characterization of the composite's porosity, interlayer spacing, and electrical conductivity.
- Fabrication and testing of a flexible asymmetric supercapacitor (ZnMoO4/CoMoS4||AC).
Main Results:
- The ZnMoO4/CoMoS4 composite exhibited a specific capacitance of 2238.75 F g−1 at 1.2 A g−1.
- The supercapacitor achieved an energy density of 58.3 Wh kg−1 at 637.7 W kg−1.
- The device retained 91.7% capacitance after 2000 cycles, demonstrating excellent stability.
Conclusions:
- The engineered composite offers enhanced ion transport and reduced charge transfer resistance.
- This work presents a scalable strategy for high-performance hybrid electrodes for flexible energy storage.
- The findings provide insights for developing next-generation supercapacitor technologies.
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