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Parity-doublet coherence times in optically trapped polyatomic molecules.

Paige Robichaud1,2, Christian Hallas3,4, Junheng Tao3,4

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Researchers achieved a record coherence time of 0.8 seconds in optically trapped CaOH molecules. This breakthrough utilizes parity-doublet states in polyatomic molecules for advanced quantum science applications.

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Area of Science:

  • Quantum information science
  • Quantum simulation
  • Precision searches for new physics

Background:

  • Polyatomic molecules possess complex internal structures suitable for quantum applications.
  • Parity-doublet states, arising from molecular degrees of freedom, are key for quantum science.
  • Linear triatomic molecules feature ℓ-type parity-doublet states in vibrational modes with predicted coherence.

Purpose of the Study:

  • To prepare and study CaOH molecules in ℓ-type parity-doublet states.
  • To achieve and measure qubit coherence times in these molecular states.
  • To investigate factors limiting coherence, such as Stark shifts and trap effects.

Main Methods:

  • Optical trapping of CaOH molecules.
  • Preparation of molecules in ℓ-type parity-doublet states.
  • Molecular spectroscopy to cancel electric fields and suppress Stark shifts.
  • Characterization of parity-dependent trap shifts.

Main Results:

  • Realization of optically trapped CaOH molecules in ℓ-type parity-doublet states.
  • Achieved a bare qubit coherence time of 0.8(2) seconds, exceeding the bending mode lifetime.
  • Identified parity-dependent trap shifts as a limiting factor for coherence.

Conclusions:

  • The achieved coherence times represent a significant milestone for polyatomic molecules in quantum science.
  • Demonstrated the potential of parity-doublet states in molecules for robust quantum applications.
  • Highlights the importance of controlling electric fields and trap interactions for future molecular quantum technologies.