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Updated: Feb 14, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Characterization of Electron Beam-Induced Polymerization of Isodecyl Methacrylate, Benzyl Methacrylate, and Their
Ilia Antonov1, Mikhail Mikhailenko1, Tatyana Shakhtshneider1
1Institute of Solid State Chemistry and Mechanochemistry SB RAS, Novosibirsk 630090, Russia.
Abstract:
The study examined the polymerization of methacrylic acid derivatives with bulky substituents (isodecyl-, benzyl-), as well as the synthesis of their copolymer through radiation initiation followed by thermal treatment. It has been discovered that the polymerization rate in equimolar monomer mixtures substantially surpasses the rate in pure monomers. We hypothesize that the substantial degree of association with the liquid monomer hinders structural rearrangements preceding polymerization. We tested this hypothesis by employing various analytical methods.
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