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Updated: Feb 14, 2026

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
From borane to metal-bound boraindene: a cascade of bond breaking and making at rhodium
Emily J Addison1, Joseph A Zurakowski1, Paul D Boyle1
1Department of Chemistry, Western University, 1151 Richmond Street, London, ON, N8K 3G6, Canada. marcus.drover@uwo.ca.
Abstract:
Few monobenzannulated 1-boraindene compounds have been reported. Here we report the synthesis of two 1-boraindenes, accessed by a bond-breaking and -making cascade from a secondary borane and diolefin, mediated by a simple pentamethylcyclopentadienyl-ligated rhodium(I) complex, [(Cp*)Rh(η2,η2-NBD)] (Cp* = C5Me5-, NBD = norbornadiene).
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