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Published on: May 22, 2018
Bridging Energy and Power Density Gap: Multi-Redox CMP/CNT Composite as High Loading Organic Cathode for Lithium-Ion
Gulraiz Tanvir1, Kamran Amin1, Zhixiang Wei1
1CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology, |University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing, China.
We developed a new conjugated microporous polymer (CMP) composite with carbon nanotubes (CNTs) for advanced lithium-ion batteries (LIBs). This material offers improved conductivity and stability, enhancing energy storage performance.
Area of Science:
- Materials Science
- Electrochemistry
- Polymer Chemistry
Background:
- Conjugated microporous polymers (CMPs) show potential for energy storage due to their properties.
- Limitations of CMPs in lithium-ion batteries (LIBs) include poor conductivity and degradation.
Purpose of the Study:
- To synthesize a dihydrophenazine-based CMP (TPA-DPZ) composite with carbon nanotubes (CNTs).
- To enhance the electrochemical performance of CMPs for LIB applications.
Main Methods:
- In situ polymerization technique to create TPA-DPZ@CNT 5% composite.
- Fabrication of cathodes with high active material loading (80%).
Main Results:
- The TPA-DPZ@CNT 5% cathode achieved a specific capacity of 128 mAh g-1 at 3.39 V.
- High capacity retention (68.34 mAh g-1 at 20 A g-1) and excellent cycling stability (89% after 10,000 cycles).
- High energy density (445 Wh kg-1) and power density (67 kW kg-1).
Conclusions:
- The synergistic effect of CMPs and CNTs overcomes limitations in organic electrodes for LIBs.
- The developed material demonstrates significant potential for high-performance energy storage devices.
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