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Decoding NASICON and Its Metal Interface for Solid-State Batteries.

Jiaqi Xu1, Taiguang Li2, Ying Wang3

  • 1Department of Mechanical and Aerospace Engineering, Syracuse University, Syracuse, New York, USA.

Advanced Materials (Deerfield Beach, Fla.)
|February 15, 2026
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Summary
This summary is machine-generated.

Sodium super ionic conductor (NASICON) solid-state batteries offer safety and high energy density. This review details NASICON

Keywords:
design fundamentals and strategieselectrolyte and metal interfacelithium NASICONsodium NASICONsolid‐state battery

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Solid-state batteries (SSBs) are advanced energy storage solutions.
  • NASICON electrolytes offer advantages like air stability and high conductivity.
  • Interfacial instability with metal anodes is a key challenge for NASICON SSBs.

Purpose of the Study:

  • To provide a comprehensive review of NASICON materials for sodium- and lithium-based SSBs.
  • To elucidate NASICON's intrinsic properties and interfacial degradation mechanisms.
  • To discuss mitigation strategies and manufacturing insights for NASICON SSBs.

Main Methods:

  • Review of fundamental crystallography, thermodynamics, and kinetics of NASICON.
  • Analysis of advanced characterization techniques for interfacial failure.
  • Synthesis of mitigation strategies for electrolyte, electrode, and interface.

Main Results:

  • Detailed understanding of NASICON's properties and degradation behaviors.
  • Identification of advanced characterization methods for failure analysis.
  • Comprehensive strategies for enhancing NASICON/metal anode interfaces.

Conclusions:

  • NASICON is a promising electrolyte for SSBs, but interfacial stability is critical.
  • Systematic understanding and targeted strategies are needed for commercialization.
  • Future research should focus on overcoming interfacial challenges for practical NASICON SSBs.