Deep eutectic hydrogel with polyphenol metal coordination and size reduced cellulose for high performance strain...

Deep eutectic solvent (DES)-based hydrogels are environmentally friendly and structurally tunable, yet their applications are often limited by poor conductivity, weak resilience and rigidity. Herein, a multifunctional hydrogel (DC-TAZn) was developed by reinforcing a choline chloride-polyacrylic acid (ChCl-PAA) matrix with size-reduced cellulose nanofibers (CNF) and dynamic tannic acid-Zn²⁺ coordination. The hydrogel exhibits high ionic conductivity (0.34 S/m), excellent stretchability (up to 807%), remarkable resilience (>99.89%), and a reliable gauge factor (1.99) for strain sensing. Additionally, DC-TAZn hydrogel shows strong adhesion, self-healing ability and antibacterial activity, while maintaining functionality under extreme conditions. This multi-synergistic hydrogel provides a sustainable strategy for designing next-generation smart hydrogels with integrated mechanical, conductive, and sensing functionalities, advancing applications in wearable electronics and intelligent human-machine interfaces.