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Related Concept Videos

Photosystem I01:27

Photosystem I

Although structurally similar to photosystem II (PSII), photosystem I (PSI) is has a different electron supplier and electron acceptor.
Both these photosystems work in concert. An excited electron from PSII is relayed to PSI via an electron transport chain in the thylakoid membrane of the chloroplast, which is comprised of the carrier molecule plastoquinone, the dual-protein cytochrome complex, and plastocyanin. As electrons move between PSII and PSI, they lose energy and must be re-energized...
Photoelectric Effect02:26

Photoelectric Effect

When light of a particular wavelength strikes a metal surface, electrons are emitted. This is called the photoelectric effect. The minimum frequency of light that can cause such emission of electrons is called the threshold frequency, which is specific to the metal. Light with a frequency lower than the threshold frequency, even if it is of high intensity, cannot initiate the emission of electrons. However, when the frequency is higher than the threshold value, the number of electrons ejected...
The Photochemical Reaction Center01:29

The Photochemical Reaction Center

Reaction centers are pigment-protein complexes that initiate energy conversion from photons to chemical entities. Therefore, photochemical reaction center is a more appropriate term that describes these complexes. The Nobel laureates Robert Emerson and William Arnold provided the first experimental evidence of photochemical reaction centers by demonstrating the participation of nearly 2,500 chlorophyll molecules for the release of just one molecule of oxygen. Despite thousands of photosynthetic...
The Z-Scheme of Electron Transport in Photosynthesis01:34

The Z-Scheme of Electron Transport in Photosynthesis

The light reactions of photosynthesis assume a linear flow of electrons from water to NADP+. During this process, light energy drives the splitting of water molecules to produce oxygen. However, oxidation of water molecules is a thermodynamically unfavorable reaction and requires a strong oxidizing agent. This is accomplished by the first product of light reactions: oxidized P680 (or P680+), the most powerful oxidizing agent known in biology. The oxidized P680 that acquires an electron from the...
Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
Nuclear Overhauser Enhancement (NOE)01:06

Nuclear Overhauser Enhancement (NOE)

Irradiation of a spin-active nucleus causes an increase or decrease in the signal intensity of neighboring nuclei that are not necessarily chemically bonded or involved in J-coupling. This phenomenon, called the nuclear Overhauser enhancement (NOE), results from through-space interactions between the nuclear spins. The NOE effect decreases with increasing internuclear distance and is generally not observed beyond 4 angstroms. In NOE, dipole-dipole interactions between neighboring spin-active...

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Updated: Jun 25, 2026

Quantification of Hydrogen Concentrations in Surface and Interface Layers and Bulk Materials through Depth Profiling with Nuclear Reaction Analysis
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Raman-Responsive Photography Strategy to Unveil Hydrogen Diffusion via a Low-Dimensional Nanocapillary.

Lan Lan1,2, Yeming Zhai1,2, Yufei Wang3

  • 1Institute of Molecular Plus, Department of Chemistry, Tianjin University, Nankai District, Tianjin 300072, China.

The Journal of Physical Chemistry Letters
|February 21, 2026
PubMed
Summary

Researchers visualized hydrogen diffusion pathways in membranes using a novel Raman spectroscopy technique. This method tracks hydrogen transport through advanced materials, aiding the design of efficient membranes for clean energy applications.

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Area of Science:

  • Materials Science
  • Chemical Engineering
  • Nanotechnology

Background:

  • Efficient hydrogen separation membranes are crucial for clean energy technologies.
  • Understanding hydrogen transport mechanisms in low-dimensional nanoarchitectures is challenging.
  • Current methods lack spatial resolution for tracking diffusion pathways.

Purpose of the Study:

  • To develop a novel method for visualizing hydrogen diffusion pathways through selective membranes.
  • To investigate hydrogen transport mechanisms in membranes based on 2D materials and frameworks.
  • To guide the design of next-generation hydrogen separation membranes.

Main Methods:

  • A Raman-responsive "photography" strategy using H2-sensitive vanadium oxide as a "photographic film".
  • Spatial-resolution tracking of hydrogen diffusion via Raman fingerprint decay at 197 cm-1.
  • Analysis of hydrogen transport in membranes made of 2D MXene, boron nitride, and zeolite.

Main Results:

  • Visualized hydrogen diffusion pathways through various selective membranes.
  • Demonstrated restricted vertical diffusion in nonporous boron nitride membranes.
  • Showed enhanced cross-plane transport with introduced pores or disrupted nanosheet assemblies.

Conclusions:

  • The Raman-based "photography" strategy effectively visualizes hydrogen diffusion pathways.
  • Membrane structure significantly influences hydrogen transport efficiency.
  • This technique provides a paradigm for designing advanced hydrogen separation membranes.