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Updated: Feb 28, 2026

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Zr-Site Lewis Acidity Determines Terpenoid Reduction Selectivity.

Kinga Gołabek1, Svetlana Kurucová1, Juan Francisco Miñambres1

  • 1Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University, Albertov 6, Prague, Praha 128 43, Czech Republic.

ACS Catalysis
|February 26, 2026
PubMed
Summary

Lewis acid zeolites, specifically Zr-beta, show distinct catalytic activities based on "open" versus "closed" Lewis acid sites. "Closed" sites favor Meerwein-Ponndorf-Verley reduction, while "open" sites promote cyclization, enabling targeted catalyst design.

Keywords:
MPV reductionZr-zeoliteacetone adsorptioncitronellalcitronellolisopulegollewis aciditytransfer hydrogenation

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