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Updated: Mar 3, 2026

Four-Dimensional Printing of Stimuli-Responsive Hydrogel-Based Soft Robots
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3D-Printed Dual Photo- and Thermally Responsive Materials for Smart Adaptability.

Tao Zhang1,2, Gianni Pacella1, Kunlin Chen1,3

  • 1Macromolecular Chemistry and New Polymeric Materials, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 3, 9747 AG Groningen, The Netherlands.

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|March 2, 2026
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Summary
This summary is machine-generated.

Researchers developed a novel 3D printing ink with dual dynamic covalent bonds (DCBs) for responsive materials. This sustainable ink offers reprocessability and dual photo- and thermal-responsive properties for advanced applications.

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Additive Manufacturing

Background:

  • Developing intelligent 3D printing materials with responsive properties is challenging for sustainable applications.
  • Existing materials often lack reprocessability, multifunctionality, and precise control over dynamic behaviors.

Purpose of the Study:

  • To create a solvent-free, photoprintable ink with dual photo- and thermally responsive properties.
  • To achieve reprocessability and multifunctionality in 3D printed materials.

Main Methods:

  • Formulation of a resin with dual dynamic covalent bonds (DCBs): dynamic disulfides and β-hydroxy esters.
  • Incorporation of photoswitchable spiropyran additives for tunable photochromic and thermochromic properties.
  • Utilizing 3D printing techniques for fabrication of responsive prototypes.

Main Results:

  • The developed ink exhibits simultaneous photo- and thermal responsiveness.
  • The material demonstrates tunable photochromic and thermochromic behaviors.
  • Printed prototypes show shape memory functionality and exceptional thermal stability.

Conclusions:

  • This work presents a sustainable and innovative solution for intelligent 3D printing materials.
  • The material bridges the gap between multifunctionality and reprocessability.
  • Advancements in responsive materials enable transformative progress in adaptive manufacturing and functional devices.