Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

The Electrical Double Layer01:30

The Electrical Double Layer

67
In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...
67
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

52.4K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
52.4K
Complexation Equilibria: Factors Influencing Stability of Complexes01:09

Complexation Equilibria: Factors Influencing Stability of Complexes

902
In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
902
Metal-Ligand Bonds02:51

Metal-Ligand Bonds

25.1K
The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
25.1K
Extraction: Advanced Methods00:56

Extraction: Advanced Methods

1.2K
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
1.2K
Formation of Complex Ions03:45

Formation of Complex Ions

26.5K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
26.5K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Revealing competitive interfacial reactions in high-energy Li-S batteries.

Nature·2026
Same author

Operando identification of anion effect on lithium nucleation and growth via in situ transmission electron microscopy.

Nature communications·2026
Same author

Precise modulation of MOF pore structures via functional group dimensions and spatial configuration for membrane separation.

Science advances·2026
Same author

In situ observations of gold deposition in a dense liquid layer at the pyrite-water interface.

Proceedings of the National Academy of Sciences of the United States of America·2026
Same author

Regulating Interfacial Nucleophilic Chemistry via Hybrid Electrolyte Enables Stable 4.8 V-Class Li-Rich||Li-Metal Batteries.

ACS nano·2025
Same author

Controlling the Distribution of Metal Elements in Core@Shell Nanosheets for Highly Efficient Direct Formic Acid Electrooxidation.

Nano letters·2025
Same journal

Formation of Bimetallic Nanoparticles via Exsolution Using a Reducible Metal Oxide Capping Layer.

ACS nano·2026
Same journal

Cold-Driven Thermoelectric Patch for Postoperative Tumor Control.

ACS nano·2026
Same journal

Chemically Fueled Interfacial Supramolecular Polymerization.

ACS nano·2026
Same journal

Tactile Neuromorphic Ion-Gated Vertical Transistor Displays Enabling Dual-Output Reservoir Computing.

ACS nano·2026
Same journal

In Situ Oxygen Shuttling within a Bilayer Electrified Membrane Enables Aeration-Free Electro-Fenton Water Purification.

ACS nano·2026
Same journal

Single Atoms as Growth Directors: From Graphene Edges to Atomically Precise Interfaces in 2D Materials.

ACS nano·2026
See all related articles

Related Experiment Video

Updated: Mar 7, 2026

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

22.4K

Lithophilic yet Inert Interfaces Strategy for Stable Lithium Metal Anodes.

Yanyun Zhang1, Guodong Zhang1, Liangping Xiao1

  • 1Department of Physics, Research Institute for Biomimetics and Soft Matter, Fujian Provincial Key Laboratory for Soft Functional Materials, Xiamen University, Xiamen 361005, P. R. China.

ACS Nano
|March 5, 2026
PubMed
Summary
This summary is machine-generated.

A novel strategy stabilizes lithium (Li) metal anodes using a black phosphorus and metal-organic framework composite (BP@MOFs). This interface enhances Li-ion migration and battery longevity, crucial for advanced energy storage.

Keywords:
Li-sulfur batteriesblack phosphorusinert interfaceslithium metal anodeslithophilic

More Related Videos

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
10:03

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques

Published on: November 11, 2013

26.2K
Three-electrode Coin Cell Preparation and Electrodeposition Analytics for Lithium-ion Batteries
10:41

Three-electrode Coin Cell Preparation and Electrodeposition Analytics for Lithium-ion Batteries

Published on: May 22, 2018

39.1K

Related Experiment Videos

Last Updated: Mar 7, 2026

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

22.4K
Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
10:03

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques

Published on: November 11, 2013

26.2K
Three-electrode Coin Cell Preparation and Electrodeposition Analytics for Lithium-ion Batteries
10:41

Three-electrode Coin Cell Preparation and Electrodeposition Analytics for Lithium-ion Batteries

Published on: May 22, 2018

39.1K

Area of Science:

  • Materials Science
  • Electrochemistry
  • Nanotechnology

Background:

  • Lithium (Li) metal anodes are key for high-energy batteries but suffer from reactivity issues.
  • Stabilizing Li metal anodes while maintaining lithophilicity is a significant challenge.

Purpose of the Study:

  • To develop a "lithophilic yet inert interfaces strategy" for stabilizing Li metal anodes.
  • To create a composite material (BP@MOFs) for an artificial interface to protect Li metal anodes.

Main Methods:

  • In situ growth of metal-organic frameworks (MOFs) on black phosphorus (BP) to form BP@MOFs.
  • Experimental and theoretical analysis to understand the interface's chemical and electronic properties.
  • Electrochemical testing of Li plating/stripping and Li-S cells.

Main Results:

  • BP@MOFs exhibit high conductivity and porous channels, facilitating Li-ion (Li+) migration.
  • Charge transfer between BP and metal ions reduces surface reactivity while preserving lithophilicity.
  • Protected Li anodes demonstrated reversible plating/stripping for over 2000 hours.
  • Li-S cells with BP@MOF-Li anodes showed 88.1% capacity retention after 500 cycles.

Conclusions:

  • The "lithophilic yet inert interfaces strategy" effectively stabilizes Li metal anodes.
  • BP@MOFs offer a promising solution for enhancing the performance and cycle life of lithium metal batteries.
  • This approach mitigates Li consumption and volume expansion issues in Li anodes.