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Colloids and Suspensions01:17

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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
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When a force is applied parallel to the top surface of a solid, it resists the applied force due to the internal frictional forces between the layers of the solid known as shearing resistance. However, when the force is removed, the shearing forces restore the original shape of the solid. Other deformation forces also cause temporary changes in shape if the forces are not beyond a threshold magnitude. Solids tend to retain their shape, making the study of their rest and motion easier. Beyond...
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First Law: Particles in Two-dimensional Equilibrium01:18

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Recall that a particle in equilibrium is one for which the external forces are balanced. Static equilibrium involves objects at rest, and dynamic equilibrium involves objects in motion without acceleration; but it is important to remember that these conditions are relative. For instance, an object may be at rest when viewed from one frame of reference, but that same object would appear to be in motion when viewed by someone moving at a constant velocity.
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Understanding the motion of particles is a fundamental aspect of classical mechanics, and the choice of the coordinate system plays a pivotal role in unraveling the complexities of their dynamics.
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The Colloidal State01:29

The Colloidal State

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The formation of a colloidal system is exemplified by an aqueous solution containing Cl− ions is introduced to another containing Ag+ ions, resulting in the precipitation of solid AgCl as extremely tiny crystals. Instead of settling out as a filterable precipitate, these crystals remain suspended in the liquid, showcasing a colloidal system.A colloidal system involves colloidal particles within the approximate range of 1 to 1000 nm in at least one dimension, dispersed in a medium called...
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Newtonian Fluid: Problem Solving01:18

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Newtonian fluids exhibit a constant viscosity, meaning their shear stress and shear strain rate are directly proportional. This property ensures a predictable and stable response to applied forces, maintaining a linear relationship between force and flow. Examples include water, air, and light oils, consistently demonstrating this proportional behavior regardless of external conditions.
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Related Experiment Video

Updated: Mar 12, 2026

Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
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Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures

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Response to dynamic shape changes in suspensions of hard rectangles.

Denis Dertli1, Thomas Speck1

  • 1Institute for Theoretical Physics IV, University of Stuttgart, Heisenbergstr. 3, 70569 Stuttgart, Germany. thomas.speck@itp4.uni-stuttgart.de.

Soft Matter
|March 11, 2026
PubMed
Summary
This summary is machine-generated.

Dynamic shape-changing nanoparticles, inspired by DNA origami, can become stuck during assembly. This study explores how altering particle shapes affects their collective behavior and ordering in simulations.

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Area of Science:

  • Soft matter physics
  • Nanoparticle self-assembly
  • Computational materials science

Background:

  • Extensive research exists on the autonomous assembly of hard nanoparticles with fixed shapes.
  • Systems involving dynamically alterable particle shapes remain largely unexplored.
  • DNA origami nanostructures provide a method for creating shape-changing nanoparticles on demand.

Purpose of the Study:

  • To investigate the structure and dynamics of nanoparticle suspensions undergoing shape changes.
  • To analyze the collective diffusion and ordering during and after shape transformation.
  • To understand the impact of shape-changing dynamics on self-assembly processes.

Main Methods:

  • Dynamic hard-particle Monte Carlo simulations were employed.
  • Simulations were conducted at constant volume using two distinct protocols.
  • The study focused on hard squares elongating into rectangles.

Main Results:

  • The cascading protocol, mimicking DNA origami, was found to be susceptible to dynamic arrest.
  • An increase in effective packing fraction was identified as the cause of dynamic arrest.
  • Collective diffusion and ordering dynamics were analyzed during shape change and relaxation.

Conclusions:

  • Dynamically altering nanoparticle shapes introduces unique challenges in self-assembly.
  • The method of shape change significantly influences the system's ability to reach equilibrium.
  • Further research is needed to optimize protocols for controlled shape-changing nanoparticle assembly.