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Updated: Mar 13, 2026

Hydrogen Production and Utilization in a Membrane Reactor
Published on: March 10, 2023
Exploring Ortho-Para Hydrogen Conversion Catalysts Based on Surface Electric Field Gradient
Hiroshi Mizoguchi1, Yuichi Shirako2, Shusaku Shoji2
1Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan.
None:
According to our hypothesis that ortho (O) to para (P) hydrogen conversion is promoted by an inhomogeneous electric field on the surface of the insulating oxide with high ionicity, we searched for OP conversion catalysts using lattice energy as an indicator of high ionicity. As a result, we found new oxide catalysts, including SiO2, γ-Al2O3, and CeO2 combined with 3d late transition metal cocatalysts. The fraction of para-H2 on 5%Fe-loaded SiO2 powder reached 50% (equilibrium value at 77 K) within 20 min. The activities of these catalysts are significantly superior to those of benchmark catalysts, such as Mn3O4. The cocatalyst nanoparticles of 1-12 nm size dispersed on the oxide catalysts adsorb hydrogen well without dissociating it. The nuclear spin state of ortho-H2 adsorbed at the asymmetric site (nonzero electric field gradient) of the oxide surface is thermally excited by nuclear quadrupole interaction, and the OP conversion rate is increased by nuclear spin relaxation.
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