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Understanding the Relationship between Gross Alpha/Beta and Radionuclide-Specific Testing in Drinking Water.

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High uranium levels in Whitehorse groundwater can exceed gross alpha screening criteria. A high uranium-234 to uranium-238 ratio complicates universal correction factors for radioactivity testing.

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Area of Science:

  • Environmental Science
  • Radiochemistry
  • Public Health

Background:

  • Public screening of water supplies for radioactivity often yields questions regarding elevated gross alpha/beta results without specific radionuclide identification.
  • Groundwater testing is crucial for assessing drinking water safety and informing public health guidelines.

Purpose of the Study:

  • To investigate the cause of gross alpha exceedances in Whitehorse, Yukon groundwater.
  • To inform revisions of Canada's drinking water guidelines for radiological parameters.

Main Methods:

  • Analysis of groundwater samples from Whitehorse, Yukon.
  • Measurement of uranium concentrations and gross alpha activity.
  • Determination of the 234U/238U activity ratio.

Main Results:

  • Uranium concentrations at guidance levels (20-30 μg L-1) caused exceedances of gross alpha screening criteria (0.5 Bq L-1).
  • Ninety-five percent of samples exhibited a 234U/238U activity ratio greater than 1.
  • The observed isotopic ratios suggest caution in applying universal correction factors for gross alpha activity.

Conclusions:

  • Uranium is a significant contributor to gross alpha activity in Whitehorse groundwater.
  • The variable 234U/238U ratio necessitates specific considerations for radiological water testing and guideline development.
  • Findings will aid in updating Canada's drinking water guidelines for radiological parameters.