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Related Concept Videos

Metal-Ligand Bonds02:51

Metal-Ligand Bonds

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
Extraction: Advanced Methods00:56

Extraction: Advanced Methods

Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is formed in...
Photoluminescence: Applications01:14

Photoluminescence: Applications

Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...

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Updated: Jul 16, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
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Recent Advances in Titanium-Based Metal-Organic Frameworks: Structure, Property, and Application in Photocatalysis.

Pengcheng Xing1, Boxuan Yang1, Lingshi Meng1

  • 1College of Chemistry and Chemical Engineering, China University of Petroleum, Qingdao 266580, China.

Molecules (Basel, Switzerland)
|March 14, 2026
PubMed
Summary

Titanium-based metal-organic frameworks (Ti-MOFs) show great potential for photocatalysis due to their unique structures and high activity. This review highlights their synthesis, properties, and applications in energy and environmental solutions.

Keywords:
photocatalysisstructure–property relationshipsynthesis strategiestitanium-based metal–organic frameworks

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Area of Science:

  • Materials Science
  • Chemistry
  • Nanotechnology

Background:

  • Metal-organic frameworks (MOFs) offer tunable properties for various applications.
  • Titanium-based MOFs (Ti-MOFs) are particularly promising for photocatalysis due to their structure and activity.

Purpose of the Study:

  • To review the latest developments in Ti-MOFs for photocatalysis.
  • To explore synthetic strategies, structural features, and performance enhancement methods.
  • To highlight applications in CO2 reduction, hydrogen evolution, and pollutant removal.

Main Methods:

  • Literature review of recent advancements in Ti-MOF research.
  • Analysis of structure-property relationships in Ti-MOFs.
  • Discussion of synthetic approaches and catalytic performance enhancement.

Main Results:

  • Ti-MOFs exhibit diverse topological configurations and excellent photocatalytic activity.
  • Key applications include CO2 reduction, hydrogen evolution, and organic pollutant degradation.
  • Structure-application relationships provide insights for advanced Ti-MOF design.

Conclusions:

  • Ti-MOFs are versatile materials for high-efficiency photocatalytic conversion.
  • Further research into Ti-MOF design can lead to improved performance.
  • Ti-MOFs offer sustainable solutions for energy and environmental challenges.