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Bioinspired Unclonable 2D Photonic Crystal Patterns with Multimode Reversible Switching for Anticounterfeiting

Wenhui Tu1, Zhiliang Li1, Kai Yu1

  • 1Qingdao University of Science & Technology, State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology, Qingdao 266042, P. R. China.

ACS Applied Materials & Interfaces
|March 16, 2026
PubMed
Summary
This summary is machine-generated.

This study introduces an unclonable, tree-ring-inspired photonic crystal (PC) system for advanced anticounterfeiting. The novel design offers random, irreplicable patterns and dynamic color switching for enhanced product authentication.

Keywords:
2D photonic crystalsanticounterfeitingreversible switchingstructural colorsunclonable patterns

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Area of Science:

  • Materials Science
  • Optics
  • Nanotechnology

Background:

  • Growing demand for information security and product authentication challenges existing anticounterfeiting technologies.
  • Photonic crystal (PC)-based optical methods offer dynamic color regulation but face limitations in replication susceptibility and material fatigue.

Purpose of the Study:

  • To develop an advanced, highly secure anticounterfeiting system inspired by natural patterns.
  • To overcome the limitations of current PC-based anticounterfeiting technologies.

Main Methods:

  • Fabrication of a two-dimensional (2D) PC system using nanospheres of varying sizes within a polymer matrix (polyethylene glycol diacrylate 200-vinyl methacrylate).
  • Integration of concentric periodic structures to mimic tree rings.
  • In situ pattern formation using controlled injection and Marangoni effects.

Main Results:

  • Achieved inherently random and irreplicable "tree-ring" patterns, providing "unclonable" security features.
  • Demonstrated multi-color-switching capabilities through different wetting modes (full immersion and unilateral wetting).
  • Exhibited brilliant, angle-dependent structural colors without requiring responsive substrates.

Conclusions:

  • The proposed 2D PC system offers a robust and simplified fabrication strategy for advanced anticounterfeiting.
  • The "unclonable" nature and dynamic color switching enhance verification reliability for product authentication.