2D excitonics with atomically thin lateral heterostructures

Semiconducting transition metal dichalcogenides (TMDs), such as MoSe₂and WSe₂, exhibit unique optical and electronic properties. Vertical stacking of layers of one or more TMDs, to create heterostructures, has expanded the fields of moiré physics and twistronics. Bottom-up fabrication techniques, such as chemical vapor deposition, have advanced the creation of heterostructures beyond what was possible with mechanical exfoliation and stacking. These techniques now enable the fabrication oflateralheterostructures (LHs), where two or more monolayers are covalently bonded in the plane of their atoms. At their atomically sharp interfaces, lateral heterostructures exhibit additional phenomena, such as the formation of charge-transfer excitons, in which the electron and hole reside on opposite sides of the interface. Due to the energy landscape created by differences in the band structures of the constituent materials, unique effects such as unidirectional exciton transport and excitonic lensing can be observed in LHs. This review outlines recent progress in exciton dynamics and spectroscopy of TMD-based LHs and offers an outlook on future developments in excitonics in this promising system.