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Related Concept Videos

Heterogeneous Catalysis01:22

Heterogeneous Catalysis

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Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...
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Related Experiment Video

Updated: Mar 25, 2026

A Continuous-flow Photocatalytic Reactor for the Precisely Controlled Deposition of Metallic Nanoparticles
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Porous Functional Nanomaterials for Continuous Flow Catalysis.

Yingguo Li1, Hao Chen2, Zhiyao Li2

  • 1School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, Jiangsu, People's Republic of China. liyg2022@just.edu.cn.

Nano-Micro Letters
|March 23, 2026
PubMed
Summary
This summary is machine-generated.

Porous materials are crucial for continuous flow catalysis in green chemistry, enabling efficient synthesis of chemicals and pharmaceuticals. This review details their design, application, and scale-up challenges for advanced flow chemistry.

Keywords:
Continuous flowHeterogeneous catalysisPhotocatalysisPorous materialsProcess intensification

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Millifluidics for Chemical Synthesis and Time-resolved Mechanistic Studies
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Area of Science:

  • Green Chemistry and Process Intensification
  • Heterogeneous Catalysis
  • Materials Science

Background:

  • Continuous flow technology is advancing fine chemical and pharmaceutical manufacturing.
  • Porous materials offer unique advantages as supports and catalytic platforms in flow systems.
  • Key porous material categories include MOFs, COFs, cages, silicates, monoliths, and polymeric carbon nitrides.

Purpose of the Study:

  • To systematically review the design and application of porous materials in continuous flow catalysis.
  • To elucidate structure-activity relationships and reaction-diffusion kinetics in flow reactors.
  • To address challenges and explore future directions for industrial scale-up.

Main Methods:

  • Review of recent literature on porous materials for continuous flow catalysis.
  • Analysis of various reactor types (fixed bed, packed bed, microreactors).
  • Examination of relationships between pore/electronic structure, active sites, and kinetics.

Main Results:

  • Porous materials like MOFs and COFs are effective in various flow catalysis applications (small molecule catalysis, photocatalysis, etc.).
  • Understanding catalyst structure, electronic properties, and reaction kinetics is vital for optimizing flow processes.
  • Industrial scale-up faces challenges in precise control, particle/morphology design, fluid dynamics, and long-term stability.

Conclusions:

  • Porous materials play a pivotal role in advancing flow chemistry.
  • Further research is needed for rational design of novel heterogeneous porous catalysts for industrial applications.
  • Overcoming scale-up challenges is key to realizing the full potential of porous materials in continuous flow systems.