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Magnetic enrichment meets internal standard calibration: a robust ratiometric SERS approach for sensitive thiram

Chongyang Qin1, Zhi Yu1, Danni Duan1

  • 1National Key Laboratory for Germplasm Innovation & Utilization of Horticultural Crops, College of Horticulture & Forestry Sciences, Huazhong Agricultural University, Wuhan, 430070, China.

Mikrochimica Acta
|March 26, 2026
PubMed
Abstract

No abstract available in PubMed .

Keywords:
Core-shell magnetic-plasmonic substrateMagnetic nanoparticlesPesticide residuesRaman spectrometry

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In an NMR sample, precise measurement of the absolute absorption frequencies of nuclei is difficult. A standard internal reference compound is added, and the frequency difference between the reference signal and sample signals is measured.
The internal reference compound generally used in NMR spectroscopy is tetramethylsilane (TMS). TMS is preferred because it is chemically inert, soluble in NMR solvents, and easily removable. Also, the highly shielded methyl protons in TMS yield an intense...

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