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Updated: Mar 27, 2026

Determination of the Photoisomerization Quantum Yield of a Hydrazone Photoswitch
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Published on: February 7, 2022

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Light-Assisted Akamptisomerization: Excited-State Bond-Angle Reflection (ESBAR) as a Molecular Photoswitching Element

Karine N de Andrade1, Jhonathan Rosa de Souza2,3, Paula Homem-de-Mello2

  • 1Department of Organic Chemistry, Institute of Chemistry, Universidade Federal Fluminense, Outeiro de São João Batista, Niterói, Rio de Janiero 24020-141, Brazil.

Inorganic Chemistry
|March 26, 2026
PubMed
Summary

Akamptisomerism in porphyrins can be facilitated in the excited state. Excited-state bond-angle reflection (ESBAR) lowers the energy barrier, suggesting potential photoswitching applications.

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