The Sediment-Water Partitioning Characteristics of Per- and Polyfluoroalkyl Substances (PFAS) in Urban Rivers...

Urban rivers often contain a complex mixture of contaminants including per- and polyfluoroalkyl substances (PFAS), metals, and various salts. This study aimed to investigate the sediment-water partitioning characteristics of PFAS in urban rivers and analyze the hydrochemical causes of this specific feature. We sampled paired water and sediment samples from urban rivers in a reclaimed water irrigation area in Beijing City. The average total PFAS concentrations in the river water and sediment were 28.44 ± 16.37 ng/L and 6.41 ± 4.20 ng/g dw, respectively. Short-chain PFAS from C4 to C6 and PFCA congeners dominated in the water, while long-chain PFAS above C8 and PFSA congeners dominated in the sediment. The average sediment-water ratio (Log K_d) of PFAS at each site showed an increasing trend with chain length, and was generally higher than that observed in seawater, natural rivers, and lakes, indicating a specific sediment-water partitioning behavior of PFAS in urban rivers. This difference is likely due to the distinct hydrochemical characteristics of the urban rivers, where elevated TDS, the presence of surfactants, and the coexistence of multiple heavy metal ions collectively promote PFAS adsorption onto suspended particulate matter and enhance their accumulation in sediments through sedimentation.