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MBenesAn Emerging 2D Layered Material: Synthesis, DFT Studies, and Application as Electrocatalyst for Hydrogen
Darshana Anand Upar1, Sarifa Regina Fernandes1, Narendra Nath Ghosh1
1Nano-materials Lab, Department of Chemistry, BITS-Pilani, Goa Campus, Zuarinagar, Goa 403726, India.
MBenes, a new class of 2-D materials, show promise for catalysis due to their unique properties. This review covers their structure, synthesis, and performance in the hydrogen evolution reaction (HER).
Area of Science:
- Materials Science
- Nanotechnology
- Catalysis
Background:
- MBenes are emerging 2-D layered materials with unique properties like high electrical conductivity and abundant active sites.
- Their potential applications are significant, driving research into their fundamental characteristics and synthesis.
- Theoretical predictions in 2017 were followed by experimental synthesis, confirming MBenes' existence and opening avenues for development.
Purpose of the Study:
- To review the fundamental aspects of MBenes, including their structure, stability, and synthesis.
- To highlight the challenges in MBenes research and development.
- To emphasize the performance of MBenes as electrocatalysts for the hydrogen evolution reaction (HER).
Main Methods:
- Theoretical studies predicting crystal structures and properties.
- Experimental synthesis of MBenes from MAB phases.
- Review of existing literature on MBenes' performance in HER.
Main Results:
- Discussion of theoretically predicted crystal structures, stability, and chemical compositions of MBenes.
- Overview of synthesis methods from precursor MAB phases.
- Emphasis on MBenes' performance as electrocatalysts for HER, supported by theoretical insights.
Conclusions:
- MBenes possess remarkable properties making them promising for various applications, particularly in catalysis.
- Further research is needed to overcome current challenges and fully realize the potential of MBenes.
- MBenes show significant promise as electrocatalysts for the hydrogen evolution reaction (HER).
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