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Porosity and Absorption of Aggregate01:20

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Aggregates contain pores of varying sizes; while some are completely enclosed within the particles, others open onto the surface, allowing water to penetrate. The porosity of aggregates is a major factor contributing to the overall porosity of concrete, given that aggregates constitute about three-quarters of concrete's volume.
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Solutions of Gases in Liquids
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
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In IR spectroscopy of carboxylic acids, the C=O bond shows a characteristic band between 1710 and 1760 cm⁻¹, and the O–H bond exhibits a broad band between 2500 and 3300 cm⁻¹.
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When a paint brush is immersed in water, the bristles wave freely inside the water. When it is taken out, the bristles stick together. The reason behind this effect is surface tension.
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The porosity of concrete is a measure of the void spaces within its structure. These spaces impact its strength and durability significantly. When water and cement interact, a chemical reaction called hydration creates a semi-solid paste. This paste includes combined water, making up approximately 23% of the cement's dry mass, and gel water, which fills minuscule voids known as gel pores, accounting for about 28% of the cement gel volume.
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Interfacial electrochemical methods focus on the phenomena occurring at the boundary between an electrode and a solution, as opposed to bulk methods that concentrate on the solution's overall properties. These interfacial methods are classified as either static or dynamic based on the presence of a nonzero current in the electrochemical cell and the consistency of analyte concentrations. Static methods, such as potentiometry, measure the cell's potential without any significant current...
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Related Experiment Video

Updated: Apr 1, 2026

Surface Properties of Synthesized Nanoporous Carbon and Silica Matrices
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Surface-Sensitive Characterization of Nujol Interaction with CaCO3 (104) Surfaces.

Lanna I M Sinimbu1, Jesana M Loreto1, Maria Luiza Dorneles1

  • 1Brazilian Center for Research in Physics (CBPF), Rio de Janeiro-RJ, Brazil.

Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
|March 31, 2026
PubMed
Summary

This study shows how water changes the surface of calcite, affecting how oil molecules like n-dodecane (Nujol) stick to it. Understanding this interaction is key for improving oil recovery technologies.

Keywords:
AFMCaCO3 (104)IRRASXPSadsorptionalkanesurface reactivity

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Area of Science:

  • Surface Science
  • Materials Chemistry
  • Petroleum Engineering

Background:

  • Understanding hydrocarbon-calcite interactions is crucial for optimizing oil recovery processes.
  • Surface properties of calcium carbonate (CaCO3) significantly influence wettability and oil adhesion.
  • Hydration effects on mineral surfaces can alter their chemical composition and reactivity.

Purpose of the Study:

  • To investigate the adsorption behavior of Nujol (n-dodecane) on pristine and hydrated CaCO3 (104) surfaces.
  • To elucidate the role of surface hydration on the chemical composition and topography of calcite.
  • To correlate molecular binding geometry with film formation and surface properties.

Main Methods:

  • Atomic Force Microscopy (AFM) for surface topography analysis.
  • X-ray Photoelectron Spectroscopy (XPS) for chemical composition determination.
  • Infrared Reflection-Absorption Spectroscopy (IRRAS) for molecular binding geometry investigation.

Main Results:

  • Hydration leads to a Ca2+-deficient calcite surface due to dissolution, observed via AFM and XPS.
  • Nujol forms a continuous film on pristine calcite but a discontinuous film on hydrated calcite.
  • IRRAS analysis revealed distinct molecular binding geometries corresponding to different film topographies.

Conclusions:

  • Surface hydration significantly modifies the hydrocarbon molecule-calcite interaction.
  • Altering surface composition and hydration levels can optimize oil adhesion for improved wettability alteration.
  • Findings are essential for enhancing oil recovery processes by controlling surface properties.