Related Experiment Video

Updated: Apr 2, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

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Inter-and Intramolecular (4+3) Cycloadditions With Epoxy Allylsilanes as Dienophiles

Qin Han Teo1, Yuchen Zhou2, Elizabeth H Krenske2

  • 1Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Hong Kong, P.R. China.

Chemistry, an Asian Journal
|March 31, 2026
PubMed
Summary

This study introduces a novel synthesis of methylenated cycloheptanoids using catalytic amounts of triflate (TESOTf). The method employs formal (4+3) cycloadditions, yielding diverse polycyclic compounds.

Keywords:
(4+3) cycloadditionallylsilanesmethylenecycloheptaneseven‐membered ring

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