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The Electrical Double Layer01:30

The Electrical Double Layer

167
In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...
167

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Stacking-Induced Ferroelectricity in Tetralayer Graphene.

Amit Singh1,2, Shuigang Xu3,4, Patrick Johansen Sarsfield1,2

  • 1Department of Physics and Astronomy, University of Manchester, Oxford Road, Manchester M13 9PL, U.K.

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|April 1, 2026
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Summary
This summary is machine-generated.

Ferroelectricity is achieved in ABCB tetralayer graphene by breaking symmetry. This stacking-order-induced effect enables robust, room-temperature nonvolatile memory applications.

Keywords:
ferroelectricitypolarizationratchet effectsliding ferroelectricitytetralayer graphene

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Area of Science:

  • Condensed matter physics
  • Materials science
  • Nanotechnology

Background:

  • Graphene's centrosymmetric lattice prevents ferroelectricity.
  • Mixed-stacked graphene, like ABCB tetralayer, breaks symmetry.

Purpose of the Study:

  • To demonstrate robust ferroelectric behavior in ABCB tetralayer graphene.
  • To explore the potential for nonvolatile memory applications.

Main Methods:

  • Encapsulating ABCB tetralayer graphene in hexagonal boron nitride.
  • Applying top and bottom gate modulation to observe resistance hysteresis.
  • Investigating transitions between ABCB and BCBA stacking configurations.

Main Results:

  • Robust ferroelectric behavior observed in ABCB tetralayer graphene.
  • Pronounced resistance hysteresis persisting up to room temperature.
  • Reversible layer-polarized charge reordering driving ferroelectricity.

Conclusions:

  • Stacking-order-induced symmetry breaking is a viable route to ferroelectricity.
  • ABCB tetralayer graphene shows promise for nonvolatile memory devices.
  • This research opens new avenues for exploring ferroelectricity in layered materials.