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Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
Published on: March 27, 2018
Goldstone-Mediated Polar Instability in Hexagonal Barium Titanate
Struan Simpson1, Urmimala Dey2,3, Robin Sjökvist4
1University of Warwick, Department of Chemistry, Gibbet Hill, CV4 7AL, Coventry, United Kingdom.
Abstract:
We discover a rare structural manifestation of the Goldstone paradigm in a hexagonal polytype of the prototypical ferroelectric BaTiO_{3}. First-principles calculations confirm the Goldstone character of the order parameter, while our high-resolution diffraction measurements unveil an unusual reentrant Goldstone regime manifesting as a quasicontinuous domain texture in the vicinity of the ferroelectric transition. We develop a minimal Landau model that encapsulates these observations, illustrating how U(1) symmetry can be restored at the ferroelectric transition. Our findings demonstrate how exotic Goldstone physics can be unlocked in systems dominated by highly anharmonic interactions, presenting a promising pathway to stabilize emergent polar topologies in bulk materials.
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