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Types of Reversible Electrodes

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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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Challenges of the infiltration method for halide-based solid‑state battery cathodes.

Artur Tron¹, Alexander Beutl², Andrea Paolella^2,3

¹AIT Austrian Institute of Technology GmbH, Center for Transport Technologies, Battery Technologies, Giefinggasse 2, Vienna, 1210, Austria. artur84.tron@gmail.com.

Scientific Reports

|April 5, 2026

Summary

This summary is machine-generated.

Wet processing of halide solid electrolytes for solid-state batteries causes dissolution and side reactions. This hinders ionic conductivity and performance, requiring careful solvent selection and electrode design for improved battery stability.

Keywords:

All-solid-state battery Halide solid electrolyte Infiltration Li3YCl4Br2 NCM cathode

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Area of Science:

Materials Science
Electrochemistry
Battery Technology

Background:

Halide solid electrolytes show promise for scalable solid-state batteries.
Compatibility with conventional wet-processing methods is a key challenge.

Purpose of the Study:

To investigate challenges of solvent-based infiltration for halide electrolytes in solid-state batteries.
To understand solvent-electrolyte interactions and their impact on cathode performance.

Main Methods:

Examined solvent-based infiltration of Li3YCl4Br2 electrolyte solutions into NCM622 cathodes.
Analyzed electrolyte dissolution, reprecipitation, ionic conductivity, and interfacial reactions.

Main Results:

Ethanol and DI water caused electrolyte dissolution and reprecipitation, lowering ionic conductivity.
Solvent-induced changes limited electrolyte penetration and caused uneven cathode coverage.
Interfacial side reactions between solvent, electrolyte, and cathode increased resistance and capacity fading.

Conclusions:

Fundamental incompatibilities exist between halide electrolytes and wet-infiltration processing.
Guidance provided for solvent selection, electrode porosity, and interfacial stability in solid-state batteries.