Construction of oxygen vacancy-rich molybdenum-based catalysts: enhanced oxidative desulfurization activity via...

In recent years, the regulatory mechanism of oxygen vacancies on oxidation desulfurization performance has gradually become a research hotspot. This work focused on the synthesis of an oxygen vacancy-rich MoO₃/CeO₂ catalyst. This catalyst was prepared by uniformly loading active species onto a cerium oxide (CeO₂) support via a CTAB-assisted reverse microemulsion method. Comprehensive characterization techniques and density functional theory (DFT) calculations confirm that oxygen vacancies enhance the metal-support interaction. This promotes electron transfer from the support to molybdenum (Mo), converting Mo into electron-rich active sites, which in turn facilitates the conversion of H₂O₂ into hydroxyl radicals (•OH), hence playing a pivotal role in subsequent oxidation desulfurization (ODS) processes. ODS experiments demonstrated that the 25% MoO₃/CeO₂-350-2 catalyst exhibits outstanding catalytic activity, achieving complete desulfurization of dibenzothiophene (DBT) within 35 min under optimal conditions. It also displayed excellent desulfurization efficiency for other thiophene-derived sulfides. Moreover, it maintained a high conversion efficiency of 90.63% even after 9 cycles, indicating the outstanding stability of the catalyst. This work provides new insights for designing efficient oxygen vacancy-rich catalysts.