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Published on: July 12, 2016
Sustainable lithium recovery from a spent LiFePO4 cathode via K2S2O8-assisted solid state oxidation through
Junhee Kim1, Min Hyuk Choi2, Dong Won Kim3
1Department of Materials Science and Engineering, Pukyong National University, 45 Yongso-ro, Nam-gu, Busan 48547, Republic of Korea. khkim213@pknu.ac.kr.
Abstract:
A rapid mechanochemical process using potassium persulfate (K2S2O8) was developed for lithium extraction from spent LiFePO4 cathodes. Nearly complete Li recovery (∼99.6%) was achieved within 30 min at 600 rpm, forming LiKSO4 and FePO4. Subsequent leaching and precipitation produced reusable Li3PO4, while the wastewater contained environmentally benign, fertilizer-grade K2SO4, indicating a sustainable recycling route.
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