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From phosphate removal to slow-release fertilizer: A closed-loop strategy enabled by Fe-BTC@sponge continuous-flow
Saiyang Zhang1, Jiali Cui1, Xiangyu Lu1
1College of Civil Engineering, Taiyuan University of Technology, Taiyuan, 030024, China; College of Environment and Ecology, Taiyuan University of Technology, Taiyuan, 030024, China.
Researchers developed a novel Fe-BTC@sponge composite for efficient phosphate removal from water. This sustainable material also functions as a phosphorus fertilizer, enabling resource recovery and addressing water eutrophication.
Area of Science:
- Environmental Chemistry
- Materials Science
- Chemical Engineering
Background:
- Global water eutrophication is a significant environmental issue.
- Phosphorus scarcity poses a threat to resource sustainability.
Purpose of the Study:
- To develop an efficient and sustainable technology for phosphorus recovery.
- To create a high-performance phosphate adsorbent for wastewater treatment.
Main Methods:
- Synthesis of a three-dimensional porous Fe-BTC composite on a cellulose sponge (Fe-BTC@sponge).
- Integration into a custom continuous-flow filtration system.
- Evaluation of adsorption efficiency, selectivity, and stability under dynamic conditions.
Main Results:
- Fe-BTC@sponge demonstrated high phosphate adsorption efficiency and selectivity across a wide pH range (3-11).
- The material maintained over 95% phosphate removal at 50 mL·min-1 for 24 hours.
- Adsorption mechanisms include electrostatic attraction, hydrogen bonding, and ligand exchange.
Conclusions:
- The Fe-BTC@sponge composite offers a high-performance solution for phosphate removal and resource recovery.
- The spent adsorbent can be repurposed as a slow-release phosphorus fertilizer, promoting a circular economy.
- This study presents an innovative strategy for sustainable wastewater purification.
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