Polyoxometalates (POMs) Memristors/Neuromorphic Devices: From Structure Engineering to Material and Function...

The advancement of artificial intelligence and information technologies has presented higher demands on neuromorphic computing information devices, entailing the emergence of next-generation devices. Polyoxometalates (POMs) are emerging as promising molecular nanomaterials for next-generation neuromorphic computing, providing distinct advantages over conventional metal oxides. In contrast to bulk oxides that suffer from stochastic filament formation and device-to-device variability, POMs possess atomically precise structures with discrete, multi-electron redox states that enable highly reproducible and deterministic resistive switching. Their molecular nature allows for stable, multi-level data representation through stepwise reduction in metal centers (e.g., V, W, Mo) and the emulation of essential synaptic plasticity functions. Furthermore, the exceptional structural and chemical tunability of POMs favors covalent or supramolecular functionalization, enabling precise engineering of the POM-electrode interface and controlled self-assembly on surfaces. This molecular precision not only addresses the scalability challenges of traditional memristors but also unlocks unique functionalities, such as multimodal switching coupled with visible chromic response for state visualization. Taking the advantages of intermolecular crosstalk and countercation dynamics, POM-based networks offer a pathway toward constructing three-dimensional neuronal architectures, effectively connecting molecular redox chemistry to advanced high-density neuromorphic computing paradigms.