Interplay Between Exfoliation and Functionalization Strategies for Group VI Layered Transition Metal Dichalcogenide...

The ability to efficiently tailor the surface properties of layered transition metal dichalcogenide (LTMD) dispersions is critical for optimizing performance and enabling scalable manufacturing techniques, such as spray coating and inkjet printing, for optoelectronic, energy storage, and sensing applications. Group VI LTMDs, owing to their unique properties in the monolayer architecture, offer exceptional potential; however, the properties of exfoliated dispersions are strongly dependent on the specific solution-processing techniques employed. These techniques determine the choice of subsequent surface functionalization strategies and, consequently, the characteristics of the resulting functionalized hybrids. Furthermore, the inherent heterogeneity of solution-processed dispersions-manifested, among other factors, in broad distributions of flake thickness and lateral size-remains a significant challenge and strongly influences the behavior of hybridized materials. As a result, exfoliation-method-dependent properties and dispersion heterogeneity introduce substantial complexity in the selection of appropriate surface-tailoring strategies, characterization methodologies, and data interpretation. To address these challenges, we systematically classify exfoliated Group VI LTMD dispersions according to their exfoliation methods and highlight recent findings that challenge previously accepted assumptions in the field. Finally, we provide perspectives on surface functionalization approaches for Group VI LTMDs and discuss key limitations associated with the characterization of these newly hybridized materials.