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Related Concept Videos

Metal-Ligand Bonds02:51

Metal-Ligand Bonds

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...

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Non-aqueous Electrode Processing and Construction of Lithium-ion Coin Cells
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Nanochitin as Binder in Li-Ion Battery Anodes Enabling Aqueous Processing and Superior Solid Electrolyte Interphase.

Amritha P Sandra1, Vishnu Arumughan2, Roberta Teixeira Polez2

  • 1Department of Chemical Engineering, KTH Royal Institute of Technology, SE-100 44 Stockholm, Sweden.

ACS Applied Materials & Interfaces
|April 18, 2026
PubMed
Summary

Chitin nanofibers (ChNFs) offer a sustainable, fluorine-free binder alternative for battery electrodes. Derived from fisheries waste, ChNFs enable aqueous processing and improve electrode stability and performance compared to traditional binders.

Keywords:
aqueous processingbinderschitin nanofibersgas evolutiongraphitelithium-ion battery

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Sustainable Chemistry

Background:

  • Binders are critical for battery electrode integrity and performance.
  • Poly(vinylidene difluoride) (PVDF), a common binder, faces scrutiny due to its polyfluoroalkyl nature and reliance on organic solvents.
  • Sustainable, fluorine-free binder alternatives are needed for eco-friendly battery manufacturing.

Purpose of the Study:

  • To introduce chitin nanofibers (ChNFs) as a biobased, fluorine-free binder for battery electrodes.
  • To investigate the mechanism of ChNF dispersion and stabilization of graphite.
  • To evaluate the electrochemical performance of ChNF-based electrodes compared to PVDF.

Main Methods:

  • Chitin nanofibers (ChNFs) derived from fisheries waste were used as a binder.
  • Aqueous dispersion of graphite with ChNFs was achieved without surfactants.
  • Colloidal probe microscopy, rheological analysis, and electrochemical testing were employed.
  • Material characterization included electron microscopy and X-ray photoelectron spectroscopy.

Main Results:

  • ChNFs effectively dispersed over 90% of graphite in water, forming stable suspensions.
  • ChNF-graphite dispersions exhibited suitable rheological properties for electrode coating.
  • Electrodes with 4% ChNFs showed high specific capacities and improved cycle stability over PVDF.
  • ChNF binders resulted in a more robust solid electrolyte interphase (SEI), reducing electrolyte reduction.

Conclusions:

  • Chitin nanofibers are a promising sustainable alternative to PVDF binders.
  • Aqueous processing of battery electrodes is feasible using ChNFs.
  • ChNF binders enhance electrochemical performance and electrode stability through improved SEI formation.