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Published on: June 23, 2017
Janus structure breaks the solar incidence angular constraint insu photothermal anti-icing
Cijian Zhang1, Beitao Liu1, Yang Chen2
1State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, Liaoning Technology Innovation Center of High Performance Resin Materials, Department of Polymer Science & Engineering, Dalian University of Technology, Dalian, P.R. China.
None:
Angle-sensitive sunlight absorption in state-of-the-art photothermal anti-icing surfaces becomes an Achilles' heel: geometric shadowing and Fresnel reflection critically degrade broadband harvesting under oblique (incident light >45°) or low solar irradiation (<0.3 sun). Herein, we bridge the angular-thermodynamic paradox via laser-engineered Janus microcavities, where protruding topology maximizes oblique photon capture while recessed-bottom architectures suppress thermal conduction. This dual-scale engineering enables rapid de-icing in extreme environments (within 25 min at -20 oC, 0.1 sun, 60° incidence) and sustained superhydrophobicity (156 ± 2° contact angle after 50 freeze-thaw cycles). The surface maintains frost-free operation for over 72 h under a sustained low irradiance of 0.1 sun at -30 °C, while integrating exceptional wear resistance and chemical stability. This geometry-adaptive strategy unlocks omnidirectional photothermal deicing for nonplanar architectures like circuit cables and aerospace pipelines, where conventional surfaces fail under erratic solar angles, a leap toward reliable thermal management in extreme environments.
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