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Updated: Apr 22, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
Self-Assembly Behavior of Monodisperse PEG Amphiphiles Bearing Hydrophobic Units with Distinct Molecular Shapes in
Ai Kohata1, Rei Hamaguchi1, Kazushi Kinbara1,2
1School of Life Science and Technology, Institute of Science Tokyo, Yokohama-shi, Kanagawa, Japan.
Abstract:
The shape of hydrophobic units on the self-assembly of amphiphiles in pure water remains underexplored. In this work, three types of octaethylene glycol (OEG)-appended amphiphiles bearing propeller-shaped, twisted, and planar hydrophobic units were synthesized. They formed different types of assemblies, such as liquid droplets, nanosheets, and supramolecular oligomers, suggesting the importance of molecular shape in designing the self-assembly of amphiphiles in water.
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