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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
Published on: August 12, 2013
Stabilizing CuTCNQ cathodes in sulfide-based all-solid-state organic lithium batteries via a fluoroiodinated
Wenwen Deng1,2, Ying Zhou3, Yuanyuan Quan3
1School of Materials Science and Engineering, Anhui University, 230601 Hefei, Anhui, PR China. 24177@ahu.edu.cn.
None:
A fluoroiodinated molecular modifier, C6F13I, is introduced to stabilize the CuTCNQ/Li6PS5Cl interface in sulfide-based all-solid-state organic lithium batteries. Its electrochemical activation generates a conformal LiF/LiI/organofluorinated interphase, suppressing electrolyte decomposition, preserving Li+ transport, and markedly improving the rate capability and cycling stability of the CuTCNQ cathode.
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