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Updated: Apr 25, 2026

Zinc-Sponge Battery Electrodes that Suppress Dendrites
Published on: September 29, 2020
Synergistic Interphase-Solvation Dual-Regulation Engineering via a Zwitterion Electrolyte Additive for Ultrastable Zn
Chenbo Yuan1, Hongdi Lu1, Chen Wang1
1Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), College of Physics, Jilin University, Changchun 130012, China.
A novel zwitterionic additive, 3-aminopropanesulfonic acid (APS), enhances aqueous Zn-metal batteries by preventing dendrite growth and parasitic reactions. This breakthrough promises more stable and commercially viable batteries.
Area of Science:
- Electrochemistry
- Materials Science
Background:
- Aqueous Zn-metal batteries (AZMBs) face challenges like dendrite growth and parasitic reactions, hindering commercialization.
- Existing monofunctional additives offer limited protection for Zn anodes.
Purpose of the Study:
- To introduce a novel zwitterionic additive, 3-aminopropanesulfonic acid (APS), for AZMBs.
- To elucidate the interphase-solvation dual-regulation (ISDR) mechanism enabled by APS.
Main Methods:
- Investigated APS adsorption on Zn anodes and its effect on the electric double layer.
- Analyzed the impact of APS on Zn2+ solvation structure and pH buffering.
- Tested Zn symmetric cells and Zn//Ca0.24V2O5·0.83H2O full batteries with APS additive under various current densities.
Main Results:
- APS promotes oriented (002) Zn deposition by forming a water-poor, zincophilic interphase.
- APS alters Zn2+ solvation and acts as a pH buffer, enhancing cycling stability.
- Zn symmetric cells exceeded 5540 h cycling; full batteries retained 87.3% capacity after 1800 cycles.
Conclusions:
- The ISDR mechanism effectively suppresses dendrite growth and parasitic reactions in AZMBs.
- APS additive significantly improves the cycling stability and performance of AZMBs.
- The findings provide a valuable guideline for developing practical AZMBs.
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