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A Novel Technique for Raman Analysis of Highly Radioactive Samples Using Any Standard Micro-Raman Spectrometer
Published on: April 12, 2017
Radiological hazards of alkali feldspar granite bearing radioactive minerals: Safety concerns and environmental
Mohamed Y Hanfi1, Ahmed E Abdel Gawad2
1Nuclear Materials Authority, P.O. Box 530, El-Maadi, Cairo, Egypt; Ural Federal University, St. Mira, 19, Yekaterinburg, 620002, Russia; Department of Physics, Dogus University, Dudullu-Ümraniye, Istanbul, 34775, Türkiye.
Abstract:
The alkali feldspar granite is enriched in Th-, U-, Zr-, and REE-mineralization. Thorite, uranothorite, zircon, monazite and xenotime have been recorded in the investigated granite that has been confirmed by an energy dispersive spectrometer (EDS) unit. The high variability in Th/U (0.43-33.91), U/K (0.15-25.38), and Th/K (2.09-19.00) ratios reflects the heterogeneous distribution of radioactive elements within the granite, which is influenced by the mineralogical composition of the samples investigated. The observed concentrations for U-238, Th-232, and K-40 provide essential data for evaluating the radiological hazards associated with using granite in construction. The findings revealed that the activity concentrations of these radionuclides 238U, 232Th, and 40K are 177 ± 138, 96 ± 25, and 1682 ± 372 Bq kg-1, respectively and exceeded the worldwide mean values. The high variability in 238U concentration highlights the importance of rigorous screening for specific samples, as some outliers may contribute more significantly to radiation exposure. In contrast, the more consistent 232Th and 40K distributions suggest that these radionuclides might contribute to relatively stable radiation levels when granite is used in construction materials. The results indicate that many granite samples exhibit high radiological hazard indicators, with several samples exceeding international safety limits for indoor exposure. The elevated Raeq, Dair, AED, and ELCR values emphasize the need for careful consideration of these granites in construction, particularly for indoor use.
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