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Occurrence and Washout of Health-Hazardous Chemicals in Children's Clothing
Awat Dostberg1, Tim Åström1, Ioannis Sadiktsis1
1Department of Chemistry, Stockholm University, Stockholm, Sweden.
Insights
Children's clothing can contain hazardous textile chemicals. Cotton garments show lower chemical levels after washing, but release more into sweat compared to polyester.
Area of Science:
- Environmental Chemistry
- Consumer Product Safety
- Pediatric Health
Background:
- Textile chemicals pose risks like skin sensitization, particularly for children due to their sensitive skin.
- Investigating chemical exposure from children's clothing is crucial for public health.
- Understanding chemical presence and behavior in textiles is vital for risk assessment.
Purpose of the Study:
- To quantify 50 textile chemicals in children's clothing.
- To assess the impact of laundry on chemical washout.
- To determine the migration of textile chemicals into artificial sweat.
Main Methods:
- Analysis of 60 children's garments from the Swedish market.
- Utilized coupled automated thermal desorption-gas chromatography/mass spectrometry (ATD-GC/MS).
- Conducted laundry experiments and simulated sweat migration tests.
Main Results:
- Frequent detection of non-regulated chemicals like quinolines, halogenated arylamines, phthalates, and nitrobenzenes.
- Highest chemical concentrations found for benzyl benzoate and 2-bromo-4,6-dinitroaniline.
- Polyester garments contained more chemicals; cotton showed greater washout but higher sweat migration.
Conclusions:
- Cotton garments, especially after laundering, indicate lower direct exposure.
- Cotton's higher migration into sweat suggests greater bioaccessibility.
- Fibre type significantly influences chemical exposure and health risk assessment.
Background:
Textile chemicals may constitute a hazardous exposure and lead to skin sensitization or other health problems. Children, due to their thinner, less developed skin, are more susceptible to this exposure.
Objectives:
To investigate the occurrence and levels of 50 textile chemicals in children´s skin-close clothing. Further, to investigate the washout effect of these textile chemicals and their tendencies to migrate from the textile fibres into artificial sweat.
Methods:
Screening of 60 children's clothes purchased on the Swedish retail market was performed using coupled automated thermal desorption-gas chromatography/mass spectrometry (ATD-GC/MS).
Results:
Among the most frequently occurring chemicals were non-regulated quinolines, halogenated arylamines, phthalates, and nitrobenzenes. The highest concentrations were found for benzyl benzoate, 1400 μg/g, and 2-bromo-4,6-dinitroaniline, 300 μg/g. The highest number and levels of chemicals were detected in garments made of 100% polyester, while the fewest and lowest levels were determined in light-coloured cotton. Laundry experiments revealed that cotton garments had the greatest washout effect, whereas most of the chemical content remained in 100% polyester garments even after 10 laundry cycles.
Conclusions:
Results indicate a lower exposure from the investigated cotton garments, especially after laundry. On the other hand, cotton exhibited threefold greater chemical migration into artificial sweat than polyester. The strong dependence on fibre material is important to consider when estimating the bioaccessible chemical exposure from garments and related health risks.
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