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Click/release reaction and SO2 recycling for multichannel dynamic chiroptical materials
Zhuoer Wang1, Aiyou Hao1, Pengyao Xing2
1School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, PR China.
Nature Communications
|April 25, 2026
Summary
Researchers developed a dynamic chiral material using a click-and-release reaction. This system offers tunable dual-channel chiroptical properties and structural evolution, demonstrating efficient supramolecular material construction.
Area of Science:
- Supramolecular Chemistry
- Materials Science
- Organic Chemistry
Background:
- Constructing dynamic chiral materials is challenging.
- Combined covalent and non-covalent strategies are emerging.
- Controlling chiroptical properties dynamically is key.
Purpose of the Study:
- To create a multichannel dynamic chiroptical system.
- To utilize a click-and-release reaction for material construction.
- To achieve independent control over dual-channel emissions.
Main Methods:
- Employed an inverse electron demand Diels-Alder reaction.
- Used a chiral-moiety-grafted thiophene S,S-dioxide and cyclooctyne.
- Integrated a fluorescent dye for SO2 capture and red emission.
Main Results:
- Achieved a high quantum yield green fluorescence emission.
- Observed in-situ structural evolution (nanospheres to vesicles, micro-sheets to helical nanotubes).
- Demonstrated dynamic control over dual-channel chiroptical system with independent green and red emissions.
Conclusions:
- Developed an effective strategy for chiral supramolecular materials.
- Highlighted the efficiency of in-situ reactions and byproduct recycling.
- Showcased a unique approach to dynamic chiroptical systems.
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