Oxidative Dry Reforming of Methane in a Reactor with a Porous Membrane Catalyst

Oxidative dry reforming of methane (ODRM) in a membrane reactor can become the basis for creating an energy-efficient process for converting greenhouse gases into a sought-after chemical raw material for gas chemistry. The process was carried out in a distribution mode in a reactor with a membrane porous catalyst (MPC) at a temperature of 850 °C. The reagents CH₄ and CO₂ were supplied to the MPC through a volume of retentate, and O₂ mixed with N₂ through a volume of permeate. The mixture of reaction products was removed from the shell side. In the experiment, the effect of the O₂/CO₂ ratio on the conversion of CH₄, CO₂ and O₂, as well as on the thermal effect of the process, was established. When oxygen enters the reactor during dry reforming of methane (DRM), the temperature inversion in the volumes of retentate and permeate occurs, as well as a decrease in electricity consumption in the resistor furnace. The observed effects of the ODRM process in MPC were interpreted using the hypothesis of active mass transfer occurring in pore channels. It is assumed that part of the carbon deposits in MPC will be gasified by oxygen.