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Adsorption Device Based on a Langatate Crystal Microbalance for High Temperature High Pressure Gas Adsorption in Zeolite H-ZSM-5
Published on: August 25, 2016
Gas-phase micro-solvation within zeolite confinement accelerates hydrogen isotope exchange
Hongbing Wang1, Yilin Liao1, Jiaju Tang1
1College of Materials and Chemistry& Chemical Engineering, Chengdu University of Technology, Chengdu, 610059, China. wanghongbing24@cdut.edu.cn.
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A gas-phase micro-solvation strategy is proposed to resolve the gas-liquid kinetic dilemma in hydrogen isotope exchange. Exploiting Pt@zeolite spatial confinement, trace water is precisely trapped to assemble localized interfacial water bridges. These confined networks act as dynamic proton shuttles, elegantly delocalizing severe charge polarization and slashing the spillover barrier to profoundly accelerate the reaction.
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